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スタニン(Stannine)またはスタナベンゼン(Stannabenzene)は、有機スズ化合物の1つで、ベンゼンの1つの炭素原子をスズ原子で置き換えたものである。スタニンそのものは、計算化学で研究されているが、単離はされていない。
, Stannabenzene (C5H6Sn) is the parent representative of a group of organotin compounds that are related to benzene with a carbon atom replaced by a tin atom. Stannabenzene itself has been studied by computational chemistry, but has not been isolated.
, Stannabenzen (C5H6Sn) je organická sloučenina odvozená od benzenu náhradou jednoho uhlíku atomem cínu. Samotný stannabenzen byl zkoumán pomocí metod výpočetní chemie, nebyl však izolován.
, 锡杂苯（C5H6Sn）是一组有机锡化合物的母体化合物，是将苯的一个碳原子换成锡原子得出来的。锡杂苯本身已通过计算化学研究，但仍未分离出来。
, Stannabenzeen (C5H6Sn) is de stamverbindin … Stannabenzeen (C5H6Sn) is de stamverbinding van een groep aan benzeen verwante verbindingen, waarbij een van de koolstofatomen vervangen is door een tin-atoom. Stannabenzeen zelf is nog niet gemaakt, maar van de verwante naftaleen-verbindingen zijn er een aantal bereid en beschreven. Zo is 2-stannanaftaleen stabiel in een inerte atmosfeer tot 140 °C. De binding tussen tin en koolstof is in deze verbinding beschermd tegen mogelijke reactanten door 2 zeer volumineuze functionele groepen, de tert-butylgroep aan het koolstofatoom naast tin en de nog veel grotere groep aan tin zelf, namelijk de 2,4,6-tris[bis(trimethylsilyl)methyl]fenyl-groep (kortweg de TBT-groep). De bindingslengte van de twee koolstof-tin-bindingen bedragen 202,9 en 208,1 pm, hetgeen korter is dan de bekende enkelvoudige koolstof-tin-binding (214 pm). De koolstof-koolstofbindingen vertonen weinig variatie in lengte: van 135,6 tot 144,3 pm, een indicatie voor het aromatische karakter van de verbinding.et aromatische karakter van de verbinding.
, Estanabenzeno (C5H6Sn) é o composto repres … Estanabenzeno (C5H6Sn) é o composto representativo de um grupo de compostos orgânicos contendo em sua estrutura molecular um anel benzênico com um átomo de carbono substuituido por um átomo de estanho. O estanabenzeno (1) propriamente dito é instável mas derivados de naftaleno estáveis são produzidos em laboratório. O 2-estananaftaleno 2 é estável e em atmosfera inerte a temperaturas abaixo de 140 °C. A ligação estanho-carbono neste composto é protegida de reagentes potenciais por dois grupos muito volumosos, um grupo tert-butil e o ainda maior grupo 2,4,6-tris[bis(trimetilsilil)metil]fenil ou Tbt. As duas ligações Sn-C tem comprimentos de ligação de 202,9 e 208,1 pm as quais são mais curtas que aquelas para as ligações Sn-C simples (214 pm) e comparáveis aquelas de conhecidas ligações duplas Sn=C (201,6 pm). As ligações C-C mostra, pequenas variações com comprimentos de ligação entre 135,6 e 144,3 pm sinalizando que este composto é aromático.sinalizando que este composto é aromático.
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Stannabenzene (C5H6Sn) is the parent representative of a group of organotin compounds that are related to benzene with a carbon atom replaced by a tin atom. Stannabenzene itself has been studied by computational chemistry, but has not been isolated.
, Estanabenzeno (C5H6Sn) é o composto repres … Estanabenzeno (C5H6Sn) é o composto representativo de um grupo de compostos orgânicos contendo em sua estrutura molecular um anel benzênico com um átomo de carbono substuituido por um átomo de estanho. O estanabenzeno (1) propriamente dito é instável mas derivados de naftaleno estáveis são produzidos em laboratório. O 2-estananaftaleno 2 é estável e em atmosfera inerte a temperaturas abaixo de 140 °C. A ligação estanho-carbono neste composto é protegida de reagentes potenciais por dois grupos muito volumosos, um grupo tert-butil e o ainda maior grupo 2,4,6-tris[bis(trimetilsilil)metil]fenil ou Tbt. As duas ligações Sn-C tem comprimentos de ligação de 202,9 e 208,1 pm as quais são mais curtas que aquelas para as ligações Sn-C simples (214 pm) e comparáveis aquelas de conhecidas ligações duparáveis aquelas de conhecidas ligações du
, スタニン(Stannine)またはスタナベンゼン(Stannabenzene)は、有機スズ化合物の1つで、ベンゼンの1つの炭素原子をスズ原子で置き換えたものである。スタニンそのものは、計算化学で研究されているが、単離はされていない。
, 锡杂苯（C5H6Sn）是一组有机锡化合物的母体化合物，是将苯的一个碳原子换成锡原子得出来的。锡杂苯本身已通过计算化学研究，但仍未分离出来。
, Stannabenzeen (C5H6Sn) is de stamverbindin … Stannabenzeen (C5H6Sn) is de stamverbinding van een groep aan benzeen verwante verbindingen, waarbij een van de koolstofatomen vervangen is door een tin-atoom. Stannabenzeen zelf is nog niet gemaakt, maar van de verwante naftaleen-verbindingen zijn er een aantal bereid en beschreven. Zo is 2-stannanaftaleen stabiel in een inerte atmosfeer tot 140 °C. De koolstof-koolstofbindingen vertonen weinig variatie in lengte: van 135,6 tot 144,3 pm, een indicatie voor het aromatische karakter van de verbinding.et aromatische karakter van de verbinding.
, Stannabenzen (C5H6Sn) je organická sloučenina odvozená od benzenu náhradou jednoho uhlíku atomem cínu. Samotný stannabenzen byl zkoumán pomocí metod výpočetní chemie, nebyl však izolován.
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Estanabenzeno
, スタニン
, Stannabenzeen
, Stannabenzene
, Stannabenzen
, 锡杂苯
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