| http://dbpedia.org/ontology/abstract
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Phosphanides are chemicals containing the … Phosphanides are chemicals containing the [PH2]− anion. This is also known as the phosphino anion or phosphido ligand. The IUPAC name can also be dihydridophosphate(1−). It can occur as a group -PH2 in organic compounds or ligand called phosphanido, or dihydridophosphato(1−). A related substance has PH2−. Phosphinidene (PH) has phosphorus in a −1 oxidation state. As a ligand PH2 can either bond to one atom or be in a μ2-bridged ligand across two metal atoms. With transition metals and actinides, bridging is likely unless the metal atom is mostly enclosed in a ligand. In phosphanides, phosphorus is in the −3 oxidation state. When phosphanide is oxidised, the first step is phosphinite ([H2PO]−). Further oxidation yields phosphonite ([HPO2]2−)and phosphite ([PO3]3−). The study of phosphine derivatives is unpopular, because they are unstable, poisonous and they smell bad.re unstable, poisonous and they smell bad.
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68892243
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31536
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, http://dbpedia.org/resource/Phosphonite +
, http://dbpedia.org/resource/Category:Phosphines +
, http://dbpedia.org/resource/Butyllithium +
, http://dbpedia.org/resource/Triphenylmethylsodium +
, http://dbpedia.org/resource/Calcium_phosphide +
, http://dbpedia.org/resource/Phosphaethynolate +
, http://dbpedia.org/resource/Phenyllithium +
, http://dbpedia.org/resource/Phosphite +
, http://dbpedia.org/resource/Liquid_ammonia +
, http://dbpedia.org/resource/Phosphine +
, http://dbpedia.org/resource/Carbon_monoxide +
, http://dbpedia.org/resource/Diethyl_carbonate +
, http://dbpedia.org/resource/Transition_metal_phosphido_complexes +
, http://dbpedia.org/resource/Phosphinidene +
, http://dbpedia.org/resource/Dimethoxyethane +
, http://dbpedia.org/resource/Phosphanediide +
, http://dbpedia.org/resource/Phosphanyl +
, http://dbpedia.org/resource/Space_group +
, http://dbpedia.org/resource/Phosphinite +
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| rdfs:comment |
Phosphanides are chemicals containing the … Phosphanides are chemicals containing the [PH2]− anion. This is also known as the phosphino anion or phosphido ligand. The IUPAC name can also be dihydridophosphate(1−). It can occur as a group -PH2 in organic compounds or ligand called phosphanido, or dihydridophosphato(1−). A related substance has PH2−. Phosphinidene (PH) has phosphorus in a −1 oxidation state. As a ligand PH2 can either bond to one atom or be in a μ2-bridged ligand across two metal atoms. With transition metals and actinides, bridging is likely unless the metal atom is mostly enclosed in a ligand.metal atom is mostly enclosed in a ligand.
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| rdfs:label |
Phosphanide
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