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The Ferrier carbocyclization (or Ferrier I … The Ferrier carbocyclization (or Ferrier II reaction) is an organic reaction that was first reported by the carbohydrate chemist Robert J. Ferrier in 1979. It is a metal-mediated rearrangement of enol ether pyrans to cyclohexanones. Typically, this reaction is catalyzed by mercury salts, specifically mercury(II) chloride. Several reviews have been published.ride. Several reviews have been published.
, 费里尔Ⅱ型重排反应(Ferrier Ⅱ reaction),又称费里尔成碳环反应(Ferrier carbocyclization),1979年首先由家(Robert J. Ferrier)报道。 它是金属介导的吡喃烯醇醚到环己酮衍生物的重排反应,一般是以汞盐如氯化汞或三氟乙酸汞催化。烯碳上带有取代基,如连有-OAc基时,反应也可发生。 反应综述:
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rdfs:comment |
费里尔Ⅱ型重排反应(Ferrier Ⅱ reaction),又称费里尔成碳环反应(Ferrier carbocyclization),1979年首先由家(Robert J. Ferrier)报道。 它是金属介导的吡喃烯醇醚到环己酮衍生物的重排反应,一般是以汞盐如氯化汞或三氟乙酸汞催化。烯碳上带有取代基,如连有-OAc基时,反应也可发生。 反应综述:
, The Ferrier carbocyclization (or Ferrier I … The Ferrier carbocyclization (or Ferrier II reaction) is an organic reaction that was first reported by the carbohydrate chemist Robert J. Ferrier in 1979. It is a metal-mediated rearrangement of enol ether pyrans to cyclohexanones. Typically, this reaction is catalyzed by mercury salts, specifically mercury(II) chloride. Several reviews have been published.ride. Several reviews have been published.
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rdfs:label |
费里尔Ⅱ型重排反应
, Ferrier carbocyclization
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